Europium

63

Eu

151.964(1)

  • Name: Europium
  • Symbol: Eu
  • Atomic number: 63
  • Atomic weight: 151.964(1)
  • CAS Registry ID: 7440-53-1
  • Group name: Lanthanoid
  • Period number: 6
  • Block: f-block
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Description

Europium is a lanthanide that has a shiny, silvery, white color in its natural solid state. It oxidizing in air, and will ignite in air and high temperatures. Europium has an atomic weight of 151.964, a melting point of 1519 °F, and a boiling point of 2784 °F. Some common uses of europium include: as a doper component to produce some types of glass and lasers, in the diagnosis of genetic diseases, as the re phosphor in T.V. and fluorescent lamps, and in trace element studies.

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Isolation

Europium is never found in its free state in nature, but it occurs in minerals with contain other rare elements and lanthanides. Extraction processes can be used to isolate europium from these elements.

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Europium is found in nature in the minerals bastnasite and monazite. Due to the fact that these minerals are also composed of other rare earth elements and lanthanides, the isolation process of europium is a highly complicated multi-step process. Due to the complexity of the europium isolation process, it is never performed on a small scale laboratory basis.

The extraction and isolation process of europium begins with treating the minerals it occurs in with sulfuric acid, hydrochloric acid, and sodium hydroxide. This process isolates the elements in the minerals out in their salt forms. Europium is further isolated by repeated solvent extractions and ion exchange chromatography. These processes extract europium out of solution in a chloride form. Electrolysis with sodium chloride in a graphite cell is needed to further purify the europium. The result from electrolysis yields pure europium and chlorine gas. It is not known currently whether pure europium presents any toxic hazards.


General
Name Europium
Symbol Eu
Number 63
Chemical series lanthanides
Group n/a
Period 6
Block f
Appearance silvery white
Standard atomic weight 151.964(1)  g·mol−1
Electron configuration [Xe] 4f7 6s2
Electrons per shell 2, 8, 18, 25, 8, 2
Atomic properties
Crystal structure simple cubic (body centered)
Oxidation states 3, 2 (mildly basic oxide)
Electronegativity ? 1.2 (scale Pauling)
Ionization energies 1st:  547.1  kJ·mol-1
(more) 2nd:  1085  kJ·mol-1
(more) 3rd:  2404  kJ·mol-1
Atomic radius 185  pm
Atomic radius (calc.) 231  pm
Covalent radius
Van der Waals radius
Physical properties
Phase solid
Density (near r.t.) 5.264  g·cm-3
Liquid density at m.p. 5.13  g·cm-3
Melting point 1099 K (826 °C, 1519 °F)
Boiling point 1802 K (1529 °C, 2784 °F)
Critical point
Heat of fusion 9.21  kJ·mol-1
Heat of vaporization 176  kJ·mol-1
Heat capacity (25 °C) 27.66  J·mol-1·K-1
Miscellaneous
Magnetic ordering
Electrical resistivity (r.t.) (poly) 0.900 µΩ·m
Thermal conductivity (300 K) est. 13.9  W·m−1·K−1
Thermal expansion (r.t.) (poly) 35.0 µm/(m·K)
Speed of sound (thin rod)
Young's modulus 18.2  GPa
Shear modulus 7.9  GPa
Bulk modulus 8.3  GPa
Poisson ratio 0.152
Mohs hardness
Vickers hardness 167  MPa
Brinell hardness
CAS registry number 7440-53-1

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