Magnesium

12

Mg

24.3050(6)

  • Name: Magnesium
  • Symbol: Mg
  • Atomic number: 12
  • Atomic weight: 24.3050(6)
  • CAS Registry ID: 7439-95-4
  • Group name: Alkaline earth metal
  • Period number: 3
  • Block: s-block
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Description

Magnesium is an alkaline earth metal with an atomic weight of 24.3050. In its natural state, magnesium is a silvery white solid; it has a melting point of 1202 °F, and a boiling point of 1994 °F. Magnesium is a flammable metal that reacts with water. Common uses of magnesium include: mixed with other compounds for light alloys used in aircraft, car engines, and missiles, as a reducing agent for uranium production, and for medicinal purposes in the form of milk of magnesia and Epsom salts.

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Isolation

Magnesium is not found free in nature, and there are a variety of processes used to isolate pure magnesium from other compounds.

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Magnesium is the 3rd most abundant element found in sea water, and so one of the main isolation procedures used to isolate magnesium use sea water as a source. The first step of this isolation process involves adding calcium carbonate to the sea water to form a precipitate of magnesium carbonate. The magnesium carbonate is not soluble in water, so it is filtered out and then reacted with hydrochloric acid. The second reaction with hydrochloric acid produces magnesium chloride. Pure magnesium is separated from the magnesium chloride compound through electrolysis.

Another isolation magnesium procedure uses dolomite. Dolomite is a sedimentary rock/mineral that is composed of calcium magnesium carbonate; therefore, dolomite is an important resource of pure magnesium. In this isolation process, the dolomite is heated to form calcined dolomite. The calcined dolomite is then reacted with ferrosilicon allow. The final distillation step is used to remove pure magnesium from the end products of this reaction.


General
Name Magnesium
Symbol Mg
Number 12
Chemical series alkaline earth metals
Group 2
Period 3
Block s
Appearance silvery white
Standard atomic weight 24.3050(6) g·mol−1
Electron configuration [Ne] 3s2
Electrons per shell 2, 8, 2
Atomic properties
Crystal structure hexagonal
Oxidation states 2 (strongly basic oxide)
Electronegativity 1.31 (Pauling scale)
Ionization energies 1st: 737.7 kJ·mol−1
(more) 2nd: 1450.7 kJ·mol−1
(more) 3rd: 7732.7 kJ·mol−1
Atomic radius 150 pm
Atomic radius (calc.) 145 pm
Covalent radius 130 pm
Van der Waals radius 173 pm
Physical properties
Phase solid
Density (near r.t.) 1.738 g·cm−3
Liquid density at m.p. 1.584 g·cm−3
Melting point 923 K (650 °C, 1202 °F)
Boiling point 1363 K (1090 °C, 1994 °F)
Critical point
Heat of fusion 8.48 kJ·mol−1
Heat of vaporization 128 kJ·mol−1
Heat capacity (25 °C) 24.869 J·mol−1·K−1
Miscellaneous
Magnetic ordering paramagnetic
Electrical resistivity (20 °C) 43.9 nΩ·m
Thermal conductivity (300 K) 156 W·m−1·K−1
Thermal expansion (25 °C) 24.8 µm·m−1·K−1
Speed of sound (thin rod) (r.t.) (annealed) 4940 m·s−1
Young's modulus 45 GPa
Shear modulus 17 GPa
Bulk modulus 45 GPa
Poisson ratio 0.29
Mohs hardness 2.5
Vickers hardness
Brinell hardness 260 MPa
CAS registry number 7439-95-4

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