Nickel

28

Ni

58.6934(2)

  • Name: Nickel
  • Symbol: Ni
  • Atomic number: 28
  • Atomic weight: 58.6934(2)
  • CAS Registry ID: 7440-02-0
  • Group name: (none)
  • Period number: 4
  • Block: d-block
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Description

Nickel is one of the transition metals that has a lustrous gold and metallic silver color in its natural solid state. Nickel has an atomic weight of 58.6934, a melting point of 2651 °F, and a boiling point of 5275 °F. While nickel is a reactive element, it does not oxidize easily when exposed to air. Some common uses of nickel include: as a component in magnets and coins, as a component in metallic alloys, as a component of stainless steel, as a component in nickel cast iron.

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Isolation

Nickel that is used for commercial purposes is isolated from two primary types or ores: the laterite ore minerals, and sulfide deposits.

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Laterite mineral ores are primarily composed of limonite, (Fe, Ni)O(OH), and garnierite, (Ni, Mg)3Si2O5(OH). The sulfide deposits are composed primarily of pentlandite, (Ni,Fe)9S8. Nickel is isolated using the principles of extractive metallurgy. During this isolation process, the nickel ore is heated and then undergoes reduction; this heating and reduction step results in a composition of nickel that is approximately ¾ pure. To isolate the nickel further for almost 100% purity, the Mond process is used.

During the Mond process, nickel is combined with carbon monoxide and heated to approximately 122 °F. The result of the reaction causes a volatile nickel carbonyl to form, and other impurities are left in a solid state. The nickel carbonyl is then brought into a chamber where it is exposed to high temperatures along with nickel spheres which are constantly moving; over time, the nickel carbonyl disintegrates and pure nickel is deposited into the nickel spheres forming solid nickel pellets.


General
Name Nickel
Symbol Ni
Number 28
Chemical series transition metals
Group 10
Period 4
Block d
Appearance lustrous, metallic and
Standard atomic weight 58.6934(2) g·mol−1
Electron configuration [Ar] 3d8 4s2
Electrons per shell 2, 8, 16, 2
Atomic properties
Crystal structure face centered cubic
Oxidation states 2, 3 (mildly basic oxide)
Electronegativity 1.91 (Pauling scale)
Ionization energies 1st: 737.1 kJ·mol−1
(more) 2nd: 1753.0 kJ·mol−1
(more) 3rd: 3395 kJ·mol−1
Atomic radius 135 pm
Atomic radius (calc.) 149 pm
Covalent radius 121 pm
Van der Waals radius 163 pm
Physical properties
Phase solid
Density (near r.t.) 8.908 g·cm−3
Liquid density at m.p. 7.81 g·cm−3
Melting point 1728 K (1455 °C, 2651 °F)
Boiling point 3186 K (2913 °C, 5275 °F)
Critical point
Heat of fusion 17.48 kJ·mol−1
Heat of vaporization 377.5 kJ·mol−1
Heat capacity (25 °C) 26.07 J·mol−1·K−1
Miscellaneous
Magnetic ordering ferromagnetic
Electrical resistivity (20 °C) 69.3 nΩ·m
Thermal conductivity (300 K) 90.9 W·m−1·K−1
Thermal expansion (25 °C) 13.4 µm·m−1·K−1
Speed of sound (thin rod) (r.t.) 4900 m·s−1
Young's modulus 200 GPa
Shear modulus 76 GPa
Bulk modulus 180 GPa
Poisson ratio 0.31
Mohs hardness 4.0
Vickers hardness 638 MPa
Brinell hardness 700 MPa
CAS registry number 7440-02-0

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