Tantalum

73

Ta

180.94788(

  • Name: Tantalum
  • Symbol: Ta
  • Atomic number: 73
  • Atomic weight: 180.94788(
  • CAS Registry ID: 7440-25-7
  • Group name: (none)
  • Period number: 6
  • Block: d-block
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Description

Tantalum is one of the transition metals that has a grayish blue color in its natural solid state. It is resistant to corrosion and conducts heat and electricity well. Tantalum has an atomic weight of 180.94788, a melting point of 5463 °F, and a boiling point of 9856 °F. Tantalum is most commonly used in a powder in the manufacture process of electronic components. It is also used in some metal alloys and super alloys, and as a component on surgical instruments and implants.

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Isolation

Tantalum is not found in its free state in nature, and isolation procedures are needed to extract it from compounds that it occurs in.

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Some of the minerals that tantalum is found in include euxenite, microlite, and tantalite. It also occurs in columbite in the ore coltan. The isolation process of tantalum is complex as it often occurs with niobium; the similar chemical traits of these elements makes extraction difficult and impossible to perform in a small laboratory. Commercial reduction, extraction, and isolation of tantalum from niobium involves several steps.

During tantalum isolation processing, the ore is first fused with an alkali; the resulting tantalum compound is extracted using a mixture of hydrofluoric acid. The acidic solution that is formed undergoes a liquid-liquid extraction process in order to extract tantalum salts into a ketone complex named MIBK; this extraction process removes tantalum from the niobium as niobium remains in the solution. The tantalum compound is then converted into an oxide and reduced through sodium or carbon. Tantalum is also often isolated as a by product from tin processing using smelting.


General
Name Tantalum
Symbol Ta
Number 73
Chemical series transition metals
Group 5
Period 6
Block d
Appearance gray blue
Standard atomic weight 180.94788(2)  g·mol−1
Electron configuration [Xe] 4f14 5d3 6s2
Electrons per shell 2, 8, 18, 32, 11, 2
Atomic properties
Crystal structure cubic body centered
Oxidation states 5, 4, 3 (mildly acidic oxide)
Electronegativity 1.5 (scale Pauling)
Ionization energies 1st: 761 kJ/mol
(more) 2nd: 1500 kJ/mol
(more)
Atomic radius 145  pm
Atomic radius (calc.) 200 pm
Covalent radius 138 pm
Van der Waals radius
Physical properties
Phase solid
Density (near r.t.) 16.69  g·cm−3
Liquid density at m.p. 15  g·cm−3
Melting point 3290 K (3017 °C, 5463 °F)
Boiling point 5731 K (5458 °C, 9856 °F)
Critical point
Heat of fusion 36.57  kJ·mol−1
Heat of vaporization 732.8  kJ·mol−1
Heat capacity (25 °C) 25.36  J·mol−1·K−1
Miscellaneous
Magnetic ordering
Electrical resistivity (20 °C) 131 n Ω·m
Thermal conductivity (300 K) 57.5  W·m−1·K−1
Thermal expansion (25 °C) 6.3  µm·m−1·K−1
Speed of sound (thin rod) (20 °C) 3400 m/s
Young's modulus 186 GPa
Shear modulus 69 GPa
Bulk modulus 200 GPa
Poisson ratio 0.34
Mohs hardness 6.5
Vickers hardness 873 MPa
Brinell hardness 800 MPa
CAS registry number 7440-25-7

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