Technetium

43

Tc

[98](0)

  • Name: Technetium
  • Symbol: Tc
  • Atomic number: 43
  • Atomic weight: [98](0)
  • CAS Registry ID: 7440-26-8
  • Group name: (none)
  • Period number: 5
  • Block: d-block
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Description

Technetium is a transition metal that is a bright, shiny, silvery grey metal in its natural solid state. There are no stable isotopes of technetium, and it is a radioactive element. Technetium has an atomic weight of 98, a melting point of 3915 °F, and a boiling point of 7709 °F. Some common uses of technetium include: as a radioactive isotope used in a variety of medical tests, as a catalysts in certain chemical reactions, and as a superconductor in extreme temperatures.

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Isolation

The isolation of technetium is only performed in special laboratories due the radioactive properties of the element; there are two ways in which technetium can be isolated.

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Technetium is a highly unstable element, and so it is only found very rarely in minute quantities in the earth’s crust; these small amounts present in the earth’s crust are created as a byproduct from the spontaneous fission of uranium. Most of the technetium on the earth is produced, and isolated, in large quantities as fission waste in spent nuclear fuel rods; due to the radioactive properties of this element, the tons of technetium that are produced each year from nuclear reactors cannot yet be used for large scale commercial purposes.

One another reaction can be used to isolate technetium. This reaction uses the sulfide form of technetium, or the pertechnate form of technetium, and reacts it with hydrogen under heated conditions. During this isolation reaction, either Tc2S7, or NH4TcO4, is reacted with hydrogen and heated to 2012 °F. While this isolation reaction is effective, it is not normally used as so much technetium is produced from nuclear reactors.


General
Name Technetium
Symbol Tc
Number 43
Chemical series transition metals
Group 7
Period 5
Block d
Appearance silvery gray metal
Standard atomic weight [98](0)  g·mol−1
Electron configuration [Kr] 4d5 5s2
Electrons per shell 2, 8, 18, 13, 2
Atomic properties
Crystal structure hexagonal
Oxidation states 7 (strongly acidic oxide)
Electronegativity 1.9 (scale Pauling)
Ionization energies 1st: 702 kJ/mol
(more) 2nd: 1470 kJ/mol
(more) 3rd: 2850 kJ/mol
Atomic radius 135 pm
Atomic radius (calc.) 185 pm
Covalent radius 156 pm
Van der Waals radius
Physical properties
Phase solid
Density (near r.t.) 11  g·cm−3
Liquid density at m.p.
Melting point 2430 K (2157 °C, 3915 °F)
Boiling point 4538 K (4265 °C, 7709 °F)
Critical point
Heat of fusion 33.29  kJ·mol−1
Heat of vaporization 585.2  kJ·mol−1
Heat capacity (25 °C) 24.27  J·mol−1·K−1
Miscellaneous
Magnetic ordering Paramagnetic
Electrical resistivity
Thermal conductivity (300 K) 50.6  W·m−1·K−1
Thermal expansion
Speed of sound (thin rod)
Young's modulus
Shear modulus
Bulk modulus
Poisson ratio
Mohs hardness
Vickers hardness
Brinell hardness
CAS registry number 7440-26-8

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