Tin

50

Sn

118.710(7)

  • Name: Tin
  • Symbol: Sn
  • Atomic number: 50
  • Atomic weight: 118.710(7)
  • CAS Registry ID: 7440-31-5
  • Group name: (none)
  • Period number: 5
  • Block: p-block
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Description

Tin is one of the poor metals that has a shiny silver grey color in its natural solid state. Tin is very malleable and will emit a crackling sound when it is bent due to its crystalline structure. Tin has an atomic weight of 118.710, a melting point of 449.47 °F, and a boiling point of 4716 °F. Some common uses of tin include: as a plating for steel containers used for food preservation, as an alloy in a variety of metals, as a component in solders, and in the production of window glass.

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Isolation

The isolation of tin is necessary to separate tin from deposits that it occurs in. This process is performed on a large scale commercial basis.

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The main source of tin for isolation purposes comes from placer mining. Placer mining is the mining of alluvial deposits for minerals; it can be performed using water pressure, open-pit mining, or through excavation. The mineral cassiterite is a tin oxide mineral and is the mineral that is used most for tin isolation. Once ore that contains tin is collected, the tin isolation process begins with removing the ore through a reduction reaction using coal in a reverberatory furnace; in this furnace, the tin ore is heated in a private compartment that allows it to come in contact with the combustion gases of the coal but not the coal itself. The tin is removed easily from the ore in this manner, and it is believed that tin removal from ore through coal was used by ancient peoples. Since cassiterite is a tin oxide, SnO2, the only product from this type of isolation process using coal is pure tin and carbon monoxide.


General
Name Tin
Symbol Sn
Number 50
Chemical series poor metals
Group 14
Period 5
Block p
Appearance silvery lustrous gray
Standard atomic weight 118.710(7)  g·mol−1
Electron configuration [Kr] 4d10 5s2 5p2
Electrons per shell 2, 8, 18, 18, 4
Atomic properties
Crystal structure tetragonal
Oxidation states 4, 2 (amphoteric oxide)
Electronegativity 1.96 (scale Pauling)
Ionization energies 1st:  708.6  kJ·mol−1
(more) 2nd:  1411.8  kJ·mol−1
(more) 3rd:  2943.0  kJ·mol−1
Atomic radius 145 pm
Atomic radius (calc.) 145 pm
Covalent radius 141 pm
Van der Waals radius 217 pm
Physical properties
Phase solid
Density (near r.t.) (white) 7.265  g·cm−3
Liquid density at m.p. 6.99  g·cm−3
Melting point 505.08 K (231.93 °C, 449.47 °F)
Boiling point 2875 K (2602 °C, 4716 °F)
Critical point
Heat of fusion (white) 7.03  kJ·mol−1
Heat of vaporization (white) 296.1  kJ·mol−1
Heat capacity (25 °C) (white) 27.112  J·mol−1·K−1
Miscellaneous
Magnetic ordering
Electrical resistivity (0 °C) 115 nΩ·m
Thermal conductivity (300 K) 66.8  W·m−1·K−1
Thermal expansion (25 °C) 22.0  µm·m−1·K−1
Speed of sound (thin rod) (r.t.) (rolled) 2730  m·s−1
Young's modulus 50 GPa
Shear modulus 18 GPa
Bulk modulus 58 GPa
Poisson ratio 0.36
Mohs hardness 1.5
Vickers hardness
Brinell hardness 51 MPa
CAS registry number 7440-31-5

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